Thermal stability. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. SrSO 4 (s) (thick white precipitate forms); Ca 2+ + SO 4 2-(aq) ? All of the Group 2 sulphates consist of 2+ ions attracting 2- ions, and so the only thing that matters is the distance between the ion centres. The Questions and Alkali metal sulphates are more soluble in water than alkaline earth metals. community of NEET. It also identifies and explains the trend in the solubility and thermal stability of group 2 metal compounds. Group II elements are less reactive than the corresponding Group I element in the same period, since two rather than one electron need to be lost in order to gain noble gas configuration. As we move down the group 2 the size of cations increases and sulphate is a big ion group according to its size. However, in a reaction with steam it forms magnesium oxide and hydrogen. Thermal decomposition of Group 2 carbonates The ease of thermal decomposition decreases down the group CaCO3(s ) CaO(s) + CO2(g ) Group 2 carbonates decompose on heating to produce group 2 oxides and carbon dioxide gas. FAQs on Appendix - … But group-2 carbonates are soluble in a solution of CO 2 due to formation of HCO 3-. The solubility of the Group 2 sulphates decreases down the group. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. In group 1 and 2, the nitrates and carbonates get more stable down the group. Reactivity of Group II elements increases down the group. The greater the distortion caused by the polarising ion the less stable the compound is to heat. The higher the temperature needed to decompose something, the more thermally stable it is. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. This page looks at the effect of heat on the carbonates and nitrates of the Group 2 elements – beryllium, magnesium, calcium, strontium and barium. This can be explained by the increase in ease at losing two outer electrons as we descend the group. This is affected by the radius of the cation, which is more able to polarise the anion when the cation is small and highly charged. b) Calcium is more reactive. BaSO 4 (s) (thick white precipitate forms); Sr 2+ + SO 4 2-(aq) ? 3.2k VIEWS. Answers of How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? In this microscale chemistry experiment, from the Royal Society of Chemistry, students investigate the solubility of the group 1 and 2 sulphates and carbonates by reacting small amounts of them on a clear plastic sheet over a worksheet. c i e n o t e s . Reactivity increases down the group. However, sulphates of alkaline earth metals show varied trends. Jan 07,2021 - How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? are solved by group of students and teacher of NEET, which is also the largest student This is clearly seen if we observe the reactions of magnesium and calcium in water. over here on EduRev! Top Be. Solubility of Carbonates INCREASES(opposite of group 2) from top to bottom. 1. 3.2k SHARES. However, in a reaction with steam it forms magnesium oxide and hydrogen. soon. The thermal stability of the nitrates follows the same trend as that of the carbonates, with thermal stability increasing with proton number. Thermal stability is a chemical process whereby the components of the lattice react causing decomposion to more stable products. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. … The resource is set out as teachers' notes followed by the students' page which presents the task to be investigated. Beryllium carbonate decomposing most easily. This means that beryllium carbonate decomposes at a lower temperature to the rest of the group. Even for hydroxides we have the same observations. Bottom Ba. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. | EduRev NEET Question is disucussed on EduRev Study Group … All of these carbonates are white solids, and the oxides that are produced are also white solids. The correct option is: (a) BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Explanation: In all cases, for a particular set of e.g. Thermal stability is the decomposition of compounds on heating. Properties of Sulphates of Alkali Earth Metals. Less attractions are formed with water molecules. The thermal stability of Group II carbonates increases as we descend the group. Charge Density and Polarising Power of Group 2 Metal Cations. Question bank for NEET. It however shows reversible decomposition in closed container Start studying Solubility of Group 2 Hydroxides and Sulphates. The reason, once more, is that the polarising power of the M2+ decreases as ionic radius increases. Ionisation energy decreases due to extra shielding from inner shells and increase in distance from the nucleus. This is clearly seen if we observe the reactions of magnesium and calcium in water. The term "thermal decomposition" describes splitting up a compound by heating it. MgCO3(s ) MgO(s) + CO2(g ) Thermal decomposition is defined as the use of heat to break down a reactant into more than one product The solubility of carbonates increases down the group in alkali metals (except ) . Solubility: The solubility of the sulphates in water decreases down the groups i.e. Nitrates of group -1 and group-2 metals are all soluble in water. The size of the sulphate ion is larger compared to the Group 2 cations. The loss of electrons becomes easier due to the decreasing ionisation energy required. is done on EduRev Study Group by NEET Students. This trend is explained in terms of the Group II metal ions ability to polarise the anion, the carbonate ion. More the strong bonding more thermal stability. The solubility also increases down the group for these compounds i-e., Be(OH)2 is less soluble in water as compared to Ba(OH)2. Ca(s) + H2O(l) → Ca(OH)2(aq) + H2(g) The relative decomposition temperatures are: MnSO 4 755, FeSO 4 537, CoSO 4 708, NiSO 4 675, CuSO 4 598, ZnSO 4 646, CdSO 4 816, PbSO 4 803, MgSO 4 895, CaSO 4 1149, and SrSO 4 1374°C. The increasing thermal stability of Group 2 metal salts is consistently seen. All the nitrates in this Group undergo thermal decomposition to give the metal oxide, nitrogen dioxide and oxygen. a) Virtually no reaction occurs between magnesium and cold water. Thermal stability of carbonates and nitrates. It reacts with cold water to produce an alkaline solution of calcium hydroxide and hydrogen gas is released. The thermal decomposition of eleven (II) sulphates has been studied by a combination of thermogravimetric and differential thermal analysis. solubility: sulphates of alkali metals are soluble in water. BeSO 4 Fairly soluble. The carbonates become more stable to heat as you go down the Group. However, due to the change in ionic radius (i.e. The effect of heat on the Group 2 carbonates. 100+ LIKES. Factors possibly influencing thermal stability of … With cold water we want to explain the trends, there is significant difference in terms their... Of these salts further increase on descending the group II elements react in air to form an oxide layer than! 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